https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:5582 Sat 24 Mar 2018 07:49:26 AEDT ]]> https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47588 4-p33) crystallized as a dinuclear complex, [Cu(Me₄-p3H3)OH]₂(ClO₄)₄, that could be structurally characterized. Interestingly, it turned out that in crystalline form the two bridging hydroxide ions were intact while two of the amine arms of the two ligands were protonated. DFT calculations were performed to get a better understanding of the behavior of this complex system in solution. Further protonation of two more amine ligand arms in solution was possible, still keeping the bridging hydroxide ions in place in the solid state. A related copper(II) complex system could be crystallized that contained a coordinated carbonate anion together with a protonated amine arm.]]> Mon 23 Jan 2023 14:42:36 AEDT ]]>